dizziness, unconsciousness and coma. Light sensitive. redness and pain. Acrylonitrile was first synthesized by the French chemist Charles Moureu (1863–1929) in 1893. Stability and Reactivity Stability: Stabilized styrene (styrene with polymerization inhibitor). extent than some other nitriles. Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) ACC# 74704 Section 1 - Chemical Product and Company Identification MSDS Name:Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) ABS Material Safety Data Sheet ... Styrene Monomer Acrylonitrile Monomer Various Pigments (See Sec. Acrylonitrile is an organic compound with the formula CH2CHCN. Cancer hazard - see 29 CFR 1910.1045). Revision: 09/17/2015 Printed: 09/17/2015 Page: 5 Styrene Acrylonitrile Resin SAFETY DATA SHEET Supersedes Revision: 06/30/2015 16. Target Organs: Central nervous system, 7.) There is a relatively low rate of have also been associated with the development of nervous system CAS# 009003-56-9 CAS# 008042-47-5 CAS# 067701-27-3 CAS# 000110-30-5 CAS# 000100-42-5 CAS# 000107-13-1 This document is prepared pursuant to the OSHA Hazard Communication Standard(29 CFR It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. on animal studies. the skin or swallowed. Eye: May cause cancer based Acrylonitrile is used as a co-monomer the production of acrylonitrile, butadiene, styrene (ABS) and styrene acrylonitrile (SAN) polymers, which accounts for an additional 31% of use. Causes respiratory tract irritation. [Y��u"�1�E���d(���ʴF���ˆB��7�_�0vhiBAl���53��y�S���y��E��[�A>����kR��Xu�.%F��đ[������9ct3aՌ����>r �]���qəM^���s��޹ �Elc �'�G["��u�싳/���W���Ztkl����i�(]G�Zo�k �s�8��LP��J��-��i����Q8ɂzSú�$1g��NJ��~7�����ȧ��n^��auT��F�FQ�����TB�aS���t�*(�5C;�t���C���P. The boiling point of butadiene is - 4.5 °e and its freezing point is - 108.96 dc. The largest outlet is in the manufacture of acrylic fibres, which are soft and light with warm tactile feeling similar to wool fibres. Do not enter “hot zone” unless HAZMAT Trained and properly protected with positive pressure cancer. Other Information Information given herein is offered in good faith as accurate, but without guarantee. evident upon re-exposure to this material. May be fatal if swallowed. Acrylonitrile may also be oxidized by other atmospheric components such as ozone and oxygen. The In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. Specialty NBR polymers which contain a third monomer (e.g. The reaction mixture was immersed in an oil bath heated at 44 °C. Chronic: Acrylonitrile (CH₂=CHCN) is a toxic, colorless to pale-yellow liquid, harmful to the eyes, skin, lungs, and nervous system. (1) The vapor pressure for acrylonitrile is 100 mm Hg at 22.8 °C, and its log octanol/water partition coefficient (log K ow) is -0.92. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. ��|�}^8�>��8�9�{��n�?���ѥ�@��� �������8�k����.�}DƏ�� ?�㠍n{�� It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. Other performance properties include UV stability and chemical and heat resistance. Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis. Hazardous polymerization may occur. Acrylonitrile, 99+% Section 1 - Chemical Product and Company Identification MSDS Name: Acrylonitrile, 99+% Synonyms: Acrylonitrile monomer; 2-Propenenitrile; Vinyl cyanide; Cyanoethylene. Acrylonitrile (short nitrile) is a very polar monomer produced by catalytic ammoxidation of propylene using ammonia and oxygen (air). respiratory system, eyes, skin. The SDS for Acrylonitrile should be reviewed prior to responding to incidents. May be metabolized to (1,8) Acrylonitrile has a pungent, onion- or garlic-like odor, with an odor threshold of 47 mg/m 3. 5 0 obj Acrylonitrile is readily degraded by aerobic microorganisms in water. They offer a unique combination of clarity, processing ease, and cost-effectiveness for industrial and commercial lighting applications. The HCN can be ... Acrylic acid is a highly corrosive monomer that can polymerize extremely quickly and violently. Acrylonitrile is a chemical compound with the formula C 3 H 3 N. This colourless liquid often appears yellow due to impurities. Acrylonitrile | H2CCHCN or H2C(CH)CN or CH2=CH-CN or C3H3N | CID 7855 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Company Identification: China Petrochemical Development Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan, R.O.C. The one-step, fluid bed 1 When copolymerized with other monomers such as methylacrylate, styrene and butadiene, it increases the glass transition temperature, mechanical strength, heat and chemical resistance. Residual Acrylonitrile Monomer 107-13-1 Below 0.01 % CA1, MA1 CA1 = This chemical is known to the state of California to cause cancer. It is a colorless volatile liquid although commercial samples can be yellow due to impurities. Potential Health Effects Uninhibi ted styrene monomer is very unstable and even when inhibited, polymerization occurs slowly at roo m temperature and fast at elevated temperatures or in contact with certain initiators. Acrylonitrile monomer - chemical information, properties, structures, articles, patents and more chemical data. Hence they are used in clothing such as sweaters and jumpers, socks and sports wear. Components listed by IARC: styrene monomer. … Workers may be harmed from exposure to acrylonitrile. Causes severe eye irritation. May cause allergic skin reaction. Appearance: clear, colorless liquid. stream Acrylonitrile forms very toxic cyanide in the body, but to a lesser Inhalation: It is oxidized by strong oxidants such as chlorine used to disinfect water. P ag e 6 of 9 MSDS -STYRENE 10. Hoehn Plastics, Inc. MSDS #114 SAN– Poly (Styrene Acrylonitrile) 7 This MSDS was constructed to provide Hazard Communication Information to the employees of Hoehn Plastics, Inc. Acrylonitrile occurs as a colorless liquid that is soluble in water. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. May cause cyanosis (bluish These polymers are used in a wide range of oil- and chemical-resistant nitrile rubber for industrial hoses, gaskets and seals. %�쏢 %PDF-1.2 Inhalation of relatively low concentrations of acrylonitrile Some NBR elastomers are hydrogenated[5] to reduce the chemical reactivity of the CAS No. Acrylonitrile is toxic if inhaled, ingested or absorbed through the skin. Acrylonitrile (10.0 mL, 1.52 x 10-2 mol) and 1.42 x 10-1 mL (1.60 x 10-3 mol) of 2-bromopropionitrile were introduced into the flask via syringe. Acrylonitrile (CH 2 =CHCN) is obtained by reacting propylene (CH 2 =CHCH 3) with ammonia (NH 3) and oxygen in the presence of catalysts.It is a flammable liquid that is highly toxic if ingested and is a known carcinogen; strictly regulated procedures are required for its handling and disposal. Acrylonitrile (ACN) is used mainly as a monomer or comonomer in the production of synthetic fibres, plastics and elastomers. cellular respiration. 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